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Although the Eqs (A) and (B) of the preceding example are readily solved, the method of equilibrium constants does not lend itself to standardization so as to allow a general program to be written for computer solution An alternative criterion of equilibrium, mentioned in Sec 132, is based on the fact that at equilibrium the total Gibbs energy of the system has its minimum value, as illustrated for a single reaction in Fig 131 Applied to multiple reactions, this criterion is the basis for a general scheme of computer solution The total Gibbs energy of a single-phase system as given by Eq (112) shows that:

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The problem is to find the set {ni) which minimizes Gt for specified T and P, subject to the constraints of the material balances The standard solution to this problem is based on the method of Lagrange's undetermined multipliers The procedure for gas-phase reactions is described as follows

W H AT I T TA K E S T O B E # 1

1 The first step is to formulate the constraining equations, ie, the material balances Although reacting molecular species are not conserved in a closed system, the total number of atoms of each element is constant Let subscript k identify a particular atom Then define Ak as the total number of atomic masses of the kth element in the system, as determined by the initial constitution of the system Further, let aik be the number of atoms of the kth element

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present in each molecule of chemical species i The material balance on each element k may then be written:

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Elements on this activity series can displace ions of metals lower than themselves on the list If, for example, one placed a piece of tin metal into a solution containing 2+ Cu(NO3)2(aq), the Sn would replace the Cu cation: Sn( s) + Cu( NO3 )2 (aq ) Sn( NO3 )2 (aq ) + Cu( s) Sn(s) + Cu 2+ (aq ) Sn 2+ (aq ) + Cu( s) The second equation is the net ionic form that is often required on the AP exam If a piece of copper metal was placed in a solution of Sn(NO3)2(aq) there would be no reaction, since copper is lower than tin on the activity series This table allows us to also predict that if sodium metal is placed in water, it will displace hydrogen, forming hydrogen gas: 2 Na( s) + 2 H2O( l ) 2 NaOH(aq ) + H 2 ( g ) 2 Na( s) + 2 H 2O( l ) 2 Na + (aq ) + 2 OH (aq ) + H2 ( g ) The Group IA and IIA elements on the activity table will displace hydrogen from water, but not the other metals shown All the metals above hydrogen will react with acidic solutions to produce hydrogen gas: Co( s) + 2 HCl(aq ) CoCl 2 (aq ) + H 2 (g ) Co( s) + 2 H + (aq ) Co 2+ (aq ) + H 2 ( g )

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(k = 1 , 2 , , w)

where w is the total number of elements comprising the system 2 Next, we introduce the Lagrange multipliers hk, one for each element, by multiplying each element balance by its hk:

These equations are summed over k, giving:

Halogen reactivity decreases as one goes from top to bottom in the periodic table, because of the decreasing electronegativity Therefore, a separate activity series for the halogens can be developed: F2 Cl 2 Br2 I2 The above series indicates that if chlorine gas were dissolved in a KI(aq) solution, the elemental chlorine would displace the iodide ion: Cl 2 (aq ) + 2 KI(aq ) 2 KCl(aq ) + I2 (s) Cl 2 (aq ) + 2 I (aq ) 2 Cl (aq ) + I2 (s)

.

3 Then a new function F is formed by addition of this last sum to Gt Thus,

This new function is identical with Gt, because the summation term is zero However, the partial derivatives of F and G' with respect to ni are different, because the function F incorporates the constraints of the material balances 4 The minimum value F (and G') occurs when all of the partial derivatives (aF/ani)T,p,nJ are zero We therefore differentiate the preceding equation, and set the resulting derivative equal to zero:

Since the first term on the right is the definition of the chemical potential [see Eq (1 11)], this equation can be written:

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